Carbonaceous-TiO2 nanomaterials for photocatalytic degradation of pollutants: A review

Semiconductor photocatalysis is one of most appealing and attractive technologies, which has been directly utilized to harvest solar energy for energy and environmental applications. Titanium dioxide (TiO₂) has been proved to be leading semiconductor photocatalyst for the degradation of pollutants. However, it suffers from low photocatalytic activity under visible light activation because of its intrinsic wide band gap. Various strategies have been developed to enhance TiO₂ efficiency in the visible light region. Among them TiO₂ modification with carbonaceous nanomaterials is very effective route for excellent photocatalytic activity. This critical review aims to present recent progress in the design and synthesis of carbonaceous-TiO₂ photocatalysts, covering carbon doping, activated carbon, fullerenes, carbon nanotubes and graphene. Moreover, proposed mechanisms of enhancement, effect of synthesis routes, demonstrations of performance and applications reported in literature are reviewed. Ongoing challenges and possible new directions are outlined.     

Cavitation erosion behavior of CLAM steel weld joint in liquid lead-bismuth eutectic alloy

The cavitation erosion of weld joint and base metal of China low activation martensitic(CLAM)steel in liquid lead-bismuth eutectic alloy(LBE)at 550°C was investigated to simulate the cavitation erosion of the first wall and the nuclear main pump impeller in the accelerator driven sub-critical system(ADS).A suit of ultrasonic cavitation facility was self-designed to study the cavitation erosion.By studying the surface micro topography,roughness and mean pit depth of the tested specimens,it was found that some crater clusters and large scale cracks appeared on the tested specimen surface after the formation of numerous single craters,and the base metal exhibited much better cavitation erosion resistance than the weld bead due to the difference in their mechanical properties and microstructures.In addition,by comparing the results of static corrosion and cavitation erosion,it could be concluded that the cavitation erosion and the dissolution and oxidation corrosion in liquid LBE would accelerate mutually.     

Synergistic Flame-retardant Effect and Mechanism of Nitrogen–Phosphorus-Containing Compounds for Glass Fiber-reinforced Polyamide 66

The system based on aluminum phosphinate (OP) and melamine polyphosphate was applied in flame-retardant glass fiber-reinforced polyamide 66. From a qualitative and quantitative point of view, the incorporation of OP played a positive role in obtaining the homodisperse of flame-retardant particles throughout the composites. A two-step cooling mode during the degradation process was established to play an effective role in absorbing heat to retard the flame spread rate and provide enough time for barrier generation. In condensed phase, the cross-linked structure formed in residue promoted the construction of the high-quality barrier layer.     

分析无机絮凝剂混凝机理中的力化学因素

以混凝机理为基础,建立了无机絮凝剂的混凝物理模型。通过混凝物理模型与无机絮凝剂的双电层压缩机理相结合,研究无机絮凝剂和投加时的稀释比例不同产生的效果,指出无机絮凝剂的混凝机理中存在流体力化学效应。     

两亲聚合物对湿法磷酸的助滤性能及机理研究

以实验室自制单体A、丙烯酰胺(AM)、二甲基二烯丙基氯化铵(DMDAAC)为原料,过硫酸盐氧化还原体系为引发剂,采用水溶液共聚法合成一种用于湿法磷酸助滤的两亲聚合物PADA-10。对所得聚合物的助滤性能进行研究,结果表明:磷酸料浆体系中加入PADA-10后,过滤速度提高了约4.3倍,滤饼水分降低了约10.8%。对PADA-10助滤机理的初步探究结果表明:PADA-10能在一定pH值范围内中和磷石膏表面电荷,使磷石膏微晶絮凝成团,添加PADA-10后滤饼的孔隙率增加;同时,PADA-10能增强磷石膏颗粒的疏水性,使磷酸滤液表面张力降低了5.2 mN/m,磷石膏表面接触角增大了3.4°。     

On the Formation and Feature of Ideological Indoctrination Mechanism in the Qin Dynasty --As the Reason of Qin Dynasty＇s Downfall

秦朝立国之后，在确立皇权至高无上的基础上，形成了威权式思想教化机制。这一教化机制的形成对于维护秦初的国家统一和社会稳定起到了一定的作用。但当秦始皇病逝之后，威权去除，思想教化机制失灵，由此导致政治思想领域的混乱和天下反叛的并起，其结果就是秦朝的覆亡。     

管理机制与中小企业可持续发展——基于湖南省中小企业的调查研究

解决中小企业实现持续发展的问题,有助于充分发挥中小企业对经济的促进作用。本文基于湖南省十大重点行业的中小企业调查,从企业内部经营管理着手,探究实现中小企业持续发展管理机制。     

A biomechanical shoulder strain index based on stabilizing demand of shoulder joint

Abstract

Work-related shoulder joint disorders contribute considerably to absenteeism in the workplace. To identify the tasks that are stressful to the shoulder joint, a strain index was formulated based on the concept of concavity compression—a shoulder stabilizing mechanism. The magnitude and direction of the shoulder joint reaction forces were used in formulating the strain index. A two phase experiment was conducted. In Phase 1, participants performed 30 different manual handling tasks. The tasks were categorized into low, medium and high strain tasks based on their strain index values. In Phase 2, out of the 30 tasks, repetitive exertions of three tasks (low, medium and high strain index values) were simulated using three external loads (0.91, 1.81 and 2.72?kg). The muscle activity data recorded from eight shoulder muscles showed that tasks with higher strain index values induced significantly greater activation and muscle fatigue than tasks with lower strain index values.Practitioner Summary: The strain index developed in this study is a conclusive estimation of the concavity compression required for shoulder joint stabilization. It can be used to identify the activities that may contribute to the risks of shoulder disorders. Abbreviation BLS Bureau of the Labor Statistics

     

优化裂解炉操作条件的方法和案例分析

裂解炉的操作条件影响着裂解产物分布,究竟采取怎样的操作参数更能实现企业经济效益最大,这是企业生产经营面临的重要课题。介绍了综合利用线性规划模型和裂解机理模型优化裂解炉操作条件、实现企业经济效益最大的方法,列举了工厂实际应用案例,对石化企业生产经营具有参考意义。